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Creators/Authors contains: "Lohrman, Jessica_A"

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  1. ; ; ; ; ; ; (, Angewandte Chemie International Edition)
    Abstract We describe two novel hybrid receptors combining a phosphorus‐/nitrogen‐containing (PN) phosphonamidate heterocycle with urea recognition units in an arylethynyl backbone. Structural, spectroscopic and computational studies reveal that the origin of superior binding for hydrogen sulfate (HSO4−) anion is correlated with the formation of strong hetero‐complementary hydrogen bonds with the phosphonamidate motif. We further demonstrate that the hybrid host system is capable of capturing/transporting the HSO4−anion from an aqueous, biphasic system. 
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